Catalytic Decarbonylation of Epoxyaldehydes: Applications to the Preparation of Terminal Epoxides

被引：6

作者：

Morandi, Bill ^{[1
]}

Carreira, Erick M. ^{[1
]}

机构：

[1] ETH, Organ Chem Lab, CH-8093 Zurich, Switzerland

来源：

SYNLETT | 2009年 / 13期

基金：

瑞士国家科学基金会;

关键词：

asymmetric synthesis; decarbonylation; epoxides; homogenous catalysis; rhodium; ASYMMETRIC EPOXIDATION; HYDROGEN-PEROXIDE; ALDEHYDES; COMPLEXES;

D O I：

10.1055/s-0029-1217562

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A catalytic decarbonylation reaction for epoxyaldehydes is reported. This reaction may be sequentially used with known asymmetric methods to access optically active mono- and disubstituted terminal epoxides, as illustrated for a key example.

引用

页码：2076 / 2078

页数：3

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