1,2-dithioglycol functionalised carbon nitride quantum dots as a "turn - off" fluorescent sensor for mercury ion detection

A kind of 1,2-dithioglycol (DTG) functionalised carbon nitride quantum dots (DTG-CNQDs) was designed for the first time by modifying DTG on the surface of carbon nitride quantum dots (CNQDs). The as-prepared DTG-CNQDs exhibit strong blue fluorescence under ultraviolet light and have a high quantum yield of 27%. Experiments show that Hg2+ has a good quenching effect on the fluorescence of DTG-CNQDs. In phosphate buffer (PBS, 10mM, pH 6.0), the fluorescence quenching rate (F-0/F) has a good linear relationship with the concentration of Hg2+ in the range of 0.020-0.50 mu M with detection limit of 0.63nM. This fluorescent probe possesses high sensitivity and good selectivity, which can be applied in the rapid detection of Hg2+ in tap and lake water samples.