Near-infrared quantum cutting in Tm3+/Yb3+-doped phosphate glasses

被引：10
|
作者：
Shi, Dong-Yang [1 ]
Lin, She-bao [1 ,2 ]
Zhao, Xiao-xia [3 ]
Feng, Ai-ling [1 ]
Xu, Qiang [1 ]
机构：
[1] Baoji Univ Arts & Sci, Inst Phys & Optoelect Technol, Baoji 721016, Peoples R China
[2] Adv Titanium Alloys & Funct Coatings Cooperat Inn, Baoji 721016, Peoples R China
[3] Henan Polytech Univ, Sch Phys & Elect Informat Engn, Jiaozuo 454003, Henan, Peoples R China
来源：
RESULTS IN PHYSICS | 2020年 / 19卷
基金：
中国国家自然科学基金;
关键词：
Phosphate glasses; Tm3+/Yb3+; Quantum cutting; MU-M EMISSION; ENERGY-TRANSFER; SOLAR-CELLS; DOWNCONVERSION LUMINESCENCE; TM3+; YB3+;
D O I：
10.1016/j.rinp.2020.103411
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A series of phosphate glasses with compositions of 30SrO-60P(2)O(5)-10Na(2)O-0.5Tm(2)O(3)-xYb(2)O(3)(x = 0, 1, 5, 9, 11 in mol%) were manufactured by melt-casting method, the quantum cutting between the Tm3+ and Yb3+ in the phosphate glasses is investigated, the energy transfer from Tm3+:(1)G(4) to Yb3+:F-2(5/2) is proved. According to calculate, the highest quantum efficiency is up to 159.9%, the emission wavelength is at 1020 nm, matching the energy band gap of a silicon solar cell well, therefor, these phosphate glasses could potentially be used in silicon solar cells.
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页数：4
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