Highly Efficient Formylation of Alcohols, Thiols and Aniline Derivatives by a Heterogeneous (HCOOH/SiO2) System under Microwave Irradiation and Solvent-free Conditions

被引：0
|
作者：
Ghorbani-Vaghei, Ramin [1 ]
Veisi, Hojat [1 ]
Amiri, Mostafa [1 ]
Chegini, Mohammad [1 ]
Karimi, Mehdi [1 ]
Dadamahaleh, Somayeh Akbari [1 ]
Sedrpoushan, Alireza [2 ]
机构：
[1] Bu Ali Sina Univ, Dept Organ Chem, Fac Chem, Hamadan, Iran
[2] IROST, Dept Ind Chem, Tehran, Iran
来源：
SOUTH AFRICAN JOURNAL OF CHEMISTRY-SUID-AFRIKAANSE TYDSKRIF VIR CHEMIE | 2009年 / 62卷
关键词：
Alcohols; anilines; SiO2; HCOOH; microwave irradiation; solvent-free conditions; CATALYTIC AMOUNT; N-FORMYLATION; ESTERIFICATION REACTION; SELECTIVE FORMYLATION; MIXED ANHYDRIDES; CARBOXYLIC-ACIDS; ETHYL FORMATE; LEWIS-ACID; ESTERS; ACETYLATION;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple, rapid and efficient microwave-assisted procedure for the formylation of aniline derivatives and alcohols, using a heterogeneous (HCOOH/SiO2) system under solvent-free conditions is reported. The method is applied to a set of amines, alcohols and thiols and short reaction times (<10 min) with high yields are reported. This protocol introduces a practical and viable green technology of solvent-free and catalyst-free reactions.
引用
收藏
页码：39 / 43
页数：5
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