Sampling, Filtering, and Analysis Protocols to Detect Black Carbon, Organic Carbon, and Total Carbon in Seasonal Surface Snow in an Urban Background and Arctic Finland (>60° N)

被引:11
|
作者
Meinander, Outi [1 ]
Heikkinen, Enna [1 ]
Aurela, Minna [1 ]
Hyvarinen, Antti [1 ]
机构
[1] Finnish Meteorol Inst, Erik Palmeninaukio 1, Helsinki 00560, Finland
基金
芬兰科学院;
关键词
snow; seasonal; black carbon; organic carbon; brown carbon; carbon; urban background; Arctic; protocol; procedure; LIGHT-ABSORBING IMPURITIES; ELEMENTAL CARBON; ALBEDO; ATMOSPHERE; ABSORPTION; SODANKYLA; SOOT;
D O I
10.3390/atmos11090923
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Black carbon (BC), organic carbon (OC), and total carbon (TC) in snow are important for their climatic and cryospheric effects. They are also part of the global carbon cycle. Atmospheric black and organic carbon (including brown carbon) may deposit and darken snow surfaces. Currently, there are no standardized methods for sampling, filtering, and analysis protocols to detect carbon in snow. Here, we describe our current methods and protocols to detect carbon in seasonal snow using the OCEC thermal optical method, a European standard for atmospheric elemental carbon (EC). We analyzed snow collected within and around the urban background SMEARIII (Station for Measuring Ecosystem-Atmosphere Relations) at Kumpula (60 degrees N) and the Arctic GAW (Global Atmospheric Watch) station at Sodankyla (67 degrees N). The median BC, OC, and TC in snow samples (n(tot) = 30) in Kumpula were 1118, 5279, and 6396 ppb, and in Sodankyla, they were 19, 1751, and 629 ppb. Laboratory experiments showed that error due to carbon attached to a sampling bag (n = 11) was <0.01%. Sonication slightly increased the measured EC, while wetting the filter or filtering the wrong side up indicated a possible sample loss. Finally, we discuss the benefits and drawbacks of OCEC to detect carbon in snow.
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页数:16
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