Infrared laser spectroscopy of imidazole complexes in helium nanodroplets: Monomer, dimer, and binary water complexes

被引：44
|
作者：
Choi, Myong Yong [1 ]
Miller, Roger E. [1 ]
机构：
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
来源：
JOURNAL OF PHYSICAL CHEMISTRY A | 2006年 / 110卷 / 30期
关键词：
D O I：
10.1021/jp0624146
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Infrared laser spectroscopy has been used to characterize imidazole (IM), imidazole dimer (IMD), and imidazole-water (IMW) binary systems formed in helium nanodroplets. The experimental results are compared with ab initio calculations reported here. Vibrational transition moment angles provide conclusive assignments for the various complexes studied here, including IM, one isomer of IMD, and two isomers of the IMW binary complexes.
引用
收藏
页码：9344 / 9351
页数：8
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