Photocatalytic formation of hydrogen in aqueous-alcohol solutions of cobalt cyanide complexes

被引：3
|
作者：
Smirnova, EV [1 ]
Ermakov, VI [1 ]
Rozenkevich, MB [1 ]
机构：
[1] Mendeleev Univ Chem Technol, Moscow 125190, Russia
来源：
KINETICS AND CATALYSIS | 2000年 / 41卷 / 01期
关键词：
Cyanides - Hydrogen - Nuclear magnetic resonance spectroscopy - Organic solvents - Solvation;
D O I：
10.1007/BF02756140
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The dependence of the parameters of the photocatalytic hydrogen formation in aqueous-alcohol (ethanol or isopropanol) solutions of cobalt cyanide on the compositions of binary and ternary solvents is studied. Experimental data are interpreted using H-1 NMR spectra of the solvents. The experimental observations are explained by possible solvation equilibria in the solutions. This photocatalytic system is a hypothetical model for the determination of relative solvation abilities of various organic compounds.
引用
收藏
页码：48 / 51
页数：4
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