Electrolyte additive strategy enhancing the electrochemical performance of a soft-packed LiCoO2//graphite full cell

被引:5
|
作者
Su, Hongjie [1 ]
Xie, Zezhong [1 ]
Feng, Jin [1 ]
Wang, Qiushi [1 ]
Zhou, Junyi [1 ]
Fu, Qishan [2 ]
Meng, Tao [1 ]
Huang, Binbin [1 ]
Meng, Changgong [3 ,4 ]
Tong, Yexiang [1 ]
机构
[1] Sun Yat Sen Univ, Sch Chem, MOE Key Lab Bioinorgan & Synthet Chem, Key Lab Low Carbon Chem & Energy Conservat Guangd, Guangzhou 510275, Peoples R China
[2] Sun Yat Sen Univ, Sch Mat Sci & Engn, Guangzhou 510275, Peoples R China
[3] Dalian Univ Technol, Sch Chem, Dalian 116024, Peoples R China
[4] Dalian Univ, Sch Chem, Dalian 116024, Peoples R China
基金
中国国家自然科学基金;
关键词
LITHIUM-ION BATTERY; FLUOROETHYLENE CARBONATE FEC; HIGH-VOLTAGE; LICOO2; CATHODE; NEGATIVE-ELECTRODE; INTERFACE; STABILITY; MECHANISM; CHARGE; STATE;
D O I
10.1039/d2dt01088g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
During the development of high-capacity, ultra-stable battery electrode materials, battery performance, and safety issues are proved to be related to the properties of the electrolyte used. The employment of electrolyte additives is to improve the battery electrolyte properties. Representative commercial two-electrode LiCoO2//graphite pouch cells are used to study electrolyte additives represented by fluoroethylene carbonate (FEC) to improve the electrochemical stability of a commercial pouch full cell. The study reveals that a 1.5% FEC electrolyte additive has the best stability in the voltage range of 3.0-4.2 V.
引用
收藏
页码:8723 / 8732
页数:10
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