Two Mono- and Binuclear Zn(II) Coordination Complexes Containing 4-Pyridyl-NH-1,2,3-triazole Ligand: Syntheses, Structures and Photoluminescence Properties

被引：2
|
作者：
Lei Xue [1 ]
Chen Yun-Zhou [1 ]
Li Yuan-Xiang [1 ]
Jia Li-Hui [1 ]
Chen Yun-Feng [1 ]
机构：
[1] Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430073, Hubei, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2018年 / 34卷 / 03期
关键词：
hydrothermal synthesis; coordination chemistry; crystal structure; photoluminescence properties; PHOTOPHYSICAL PROPERTIES; SPECTROSCOPIC PROPERTIES; CRYSTAL-STRUCTURES; POLYMERS; FRAMEWORKS; AZIDES; STATES;
D O I：
10.11862/CJIC.2018.060
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two Zn(II) coordination complexes, [Zn-2(L)(2)Cl-4] (1) and [Zn(L)(2)Cl-2]center dot 2H(2)O (2) (L=4-pyridiyl-NH-1,2,3-triazole) are synthesized by reaction of ZnCl2 center dot 2H(2)O with rigid ligand L. Single crystal diffraction reveals that 1 and 2 crystallizes in space groups, P (1) over bar and P2(1)/n, respectively. In the structures of 1 and 2, supramolecular interactions play important role in forming 3D structures. Photoluminescent properties of 1 and 2 in solid state and dilute methanolic solutions have been investigated in detail.
引用
收藏
页码：545 / 550
页数：6
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