Accelerating effect of arsonium ylide for the copolymerization of acrylonitrile and α-methyl styrene

被引：0
|
作者：
Awasthi, Rita [1 ]
机构：
[1] Brahmanand PG Coll, Dept Chem, Kanpur, Uttar Pradesh, India
来源：
JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2009年 / 86卷 / 07期
关键词：
Copolymerization; p-ABTAY; rate of polymerization intrinsic viscosity; POLYMERIZATION;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
p-Acetyl benzylidene triphenyl arsonium ylide (p-ABTAY) accelerates alpha,alpha-azobisisobutyronitrile (AIBN) initiated copolymerization of acrylonitrile (AN) and alpha-methyl styrene (alpha-MS) in DMF at 65 +/- 0.1 degrees C by reducing the rate of termination. The value of energy of activation in the presence and absence of p-ABTAY is 11.0 and 9.8 kJ/mol, respectively.
引用
收藏
页码：753 / 755
页数：3
相关论文
共 50 条
  • [1] EFFECT OF A YLIDE ON RADICAL COPOLYMERIZATION OF ACRYLONITRILE WITH STYRENE
    NIGAM, SK
    SAINI, S
    SRIVASTAVA, AK
    [J]. INDIAN JOURNAL OF TECHNOLOGY, 1986, 24 (12): : 743 - 745
  • [2] THE EFFECT OF SOLVENT ON THE STYRENE ACRYLONITRILE COPOLYMERIZATION
    HILL, DJT
    LANG, AP
    MUNRO, PD
    ODONNELL, JH
    [J]. EUROPEAN POLYMER JOURNAL, 1992, 28 (04) : 391 - 398
  • [3] Effect of acrylonitrile water solubility on the suspension copolymerization of acrylonitrile and styrene
    Lu, Qun
    Weng, Zhi-Xue
    Shan, Guo-Rong
    Lai, Guo-Qiao
    Pan, Zu-Ren
    [J]. Journal of Applied Polymer Science, 2006, 101 (06): : 4270 - 4274
  • [4] Effect of acrylonitrile water solubility on the suspension copolymerization of acrylonitrile and styrene
    Lu, Qun
    Weng, Zhi-xue
    Shan, Guo-rong
    Lai, Guo-qiao
    Pan, Zu-ren
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 101 (06) : 4270 - 4274
  • [5] COPOLYMERIZATION .2. THE COPOLYMERIZATION OF ACRYLONITRILE, METHYL METHACRYLATE, STYRENE AND VINYLIDENE CHLORIDE
    LEWIS, FM
    MAYO, FR
    HULSE, WF
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1945, 67 (10) : 1701 - 1705
  • [6] Effect of solvent on the styrene-acrylonitrile copolymerization
    [J]. Hill, D.J.T., 1600, (28):
  • [7] Fullerene as radical inhibitor in polymerization of acrylonitrile initiated by arsonium ylide
    Ravindra Singh
    Deepak Srivastava
    Santosh K. Upadhyay
    [J]. Polymer Science Series B, 2012, 54 : 88 - 93
  • [8] HEAT OF COPOLYMERIZATION OF ACRYLONITRILE WITH METHYL METHACRYLATE, STYRENE, AND VINYL ACETATE
    MIYAMA, H
    FUJIMOTO, S
    [J]. JOURNAL OF POLYMER SCIENCE, 1961, 54 (160): : S32 - &
  • [9] Copolymerization of styrene, acrylonitrile and methyl methacrylate with γ-methacryloxypropyl trimethoxy silane
    [J]. Rao, V.L., 1600, (25):
  • [10] Fullerene as Radical Inhibitor in Polymerization of Acrylonitrile Initiated by Arsonium Ylide
    Singh, Ravindra
    Srivastava, Deepak
    Upadhyay, Santosh K.
    [J]. POLYMER SCIENCE SERIES B, 2012, 54 (1-2) : 88 - 93
12345