Catalytic aerobic oxidation of allylic alcohols to carbonyl compounds under mild conditions

被引：33
|
作者：
Tonucci, Lucia [1 ]
Nicastro, Marco [1 ]
d'Alessandro, Nicola [1 ]
Bressan, Mario [1 ]
D'Ambrosio, Primiano [1 ]
Morvillo, Antonino [2 ]
机构：
[1] Univ G Annunzio Chieti & Pescara, Dept Sci, I-65127 Pescara, Italy
[2] Univ Padua, Dept Chem Sci, I-35100 Padua, Italy
来源：
GREEN CHEMISTRY | 2009年 / 11卷 / 06期
关键词：
BAEYER-VILLIGER OXIDATION; MOLECULAR-OXYGEN; SELECTIVE OXIDATION; HYDROGEN-PEROXIDE; SUBSTRATE SCOPE; OXO COMPLEX; ALDEHYDES; KETONES; EFFICIENT; CONVERSIONS;
D O I：
10.1039/b813019a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new catalytic aerobic oxidation of alcohols to aldehydes under green conditions was developed (room temperature and pressure, water solution, open vials). The water-soluble platinum(II) tetrasulfophthalocyanine (PtPcS) catalyst showed the best selectivity for carbonyl derivatives, and in particular for alpha,beta-unsaturated alcohols; the reactions are slow.
引用
收藏
页码：816 / 820
页数：5
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