Three-Dimensional Chirality Transfer in Rubrene Multilayer Islands on Au(111)

被引：29

作者：

Pivetta, Marina ^{[1
]}

Bluem, Marie-Christine ^{[1
]}

Patthey, Francois ^{[1
]}

Schneider, Wolf-Dieter ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Phys Mat Condensee, CH-1015 Lausanne, Switzerland

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2009年 / 113卷 / 14期

基金：

瑞士国家科学基金会;

关键词：

FIELD-EFFECT TRANSISTORS; SINGLE-CRYSTAL; THIN-FILMS; VAPOR TRANSPORT; METAL-SURFACES; GROWTH; MORPHOLOGY; MOLECULES; FABRICATION; MICROSCOPY;

D O I：

10.1021/jp8104024

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The growth of rubrene (C42H28, 5,6,11,12-tetraphenylnaphthacene) multilayer islands up to a thickness of six layers on a Au(111) surface has been investigated by scanning tunneling microscopy. The molecules self-organize in parallel twin rows, forming mirror domains of defined local structural chirality. Each layer is composed of twin-row domains of the same structural handedness rotated by 120 degrees with respect to each other. Moreover, this structural chirality is transferred to all successive layers in the island, resulting in the formation of three-dimensional objects having a defined structural chirality. The centered rectangular surface unit cell differs from the one characteristic for the single-crystal orthorhombic phase.

引用

页码：4578 / 4581

页数：4

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