Magnetism in new classes of TTF-based charge transfer complexes

被引：0

作者：

Enoki, T ^{[1
]}

Yamazaki, H ^{[1
]}

Okabe, K ^{[1
]}

Nishijo, JI ^{[1
]}

Enomoto, K ^{[1
]}

Enomoto, M ^{[1
]}

Miyazaki, A ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2002年 / 379卷

关键词：

organic metal; molecular magnet; pi-d interaction; metal-insulator transition; spin ladder; ferromagnet;

D O I：

10.1080/713738655

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Charge transfer (CT) complexes are promising for developing molecule-based magnets, where pi-electrons play an important role. New classes of molecular magnets are presented in the TTF-based CT complexes from points of unconventional magnetism. pi-d interaction in d-electron-spin-incorporated CT complexes give anomalous effect of magnetic transition on the electron transport. The coexistence of metallic conduction and localized spin feature appears in the system located in the metal-insulator boundary. 1D metal having ferromagnetic interaction and triangle-based spin ladder system are also obtained from CT complexes.

引用

页码：131 / 140

页数：10

共 50 条

[1] Magnetic TTF-based charge-transfer complexes
Enoki, T
Miyazaki, A
CHEMICAL REVIEWS, 2004, 104 (11) : 5449 - 5477
[2] Valence-band spectra of BEDT-TTF and TTF-based magnetic charge-transfer salts
Kurmaev, EZ
Moewes, A
Chiuzbian, SG
Finkelstein, LD
Neumann, M
Turner, SS
Day, P
PHYSICAL REVIEW B, 2002, 65 (23) : 2351061 - 2351066
[3] Lanthanide complexes involving multichelating TTF-based ligands
Speed, S.
Feng, M.
Garcia, G. Fernandez
Pointillart, F.
Lefeuvre, B.
Riobe, F.
Golhen, S.
Le Guennic, B.
Totti, F.
Guyot, Y.
Cador, O.
Maury, O.
Ouahab, L.
INORGANIC CHEMISTRY FRONTIERS, 2017, 4 (04): : 604 - 617
[4] Charge transfer complexes based on BEDT-TTF vinylogues
Yu, LH
Zhu, DB
PHYSICA C, 1997, 282 : 1899 - 1900
[5] APPLICATION OF THE DIMER APPROACH FOR THE ANALYSIS OF VIBRATIONAL-SPECTRA OF BEDT TTF-BASED CHARGE-TRANSFER SALTS
KOZLOV, ME
TOKUMOTO, M
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1994, 50 (14): : 2271 - 2280
[6] Novel TTF-based molecular magnets
Enoki, T
Umeyama, T
Enomoto, M
Yamaura, J
Yamaguchi, K
Miyazaki, K
Ogura, E
Kuwatani, Y
Iyoda, M
Kikuchi, K
SYNTHETIC METALS, 1999, 103 (1-3) : 2275 - 2278
[7] Unconventional TTF-based molecular magnets
Enoki, T
Yamazaki, H
Okabe, K
Enomoto, K
Kato, T
Miyazaki, A
Ogura, E
Kuwatani, Y
Iyoda, M
SYNTHETIC METALS, 2003, 133 : 501 - 503
[8] Synthesis, crystal structures and physical properties of TTF-based conducting charge transfer salts with anions containing selenocyanate ligands
Turner, SS
Le Pévelen, D
Day, P
Prout, K
JOURNAL OF SOLID STATE CHEMISTRY, 2002, 168 (02) : 573 - 581
[9] A NEW ROUTE TOWARDS MULTISULFUR TTF-BASED COMPONENTS FOR ORGANIC METALS
KHODORKOVSKY, VY
BECKER, JY
BERNSTEIN, J
SYNTHETIC METALS, 1993, 56 (01) : 1931 - 1935
[10] Radical cation salts and charge transfer complexes based on functionalized TTF derivatives
Legros, J.-P.
Dahan, F.
Binet, L.
Fabre, J.-M.
Synthetic Metals, 1999, 102 (1 -3 pt 2): : 1632 - 1633

← 1 2 3 4 5 →