Electrochromic behavior of WO3 thin films prepared by GLAD

被引：36
|
作者：
Yuan, Jiali [1 ,2 ,3 ]
Wang, Bin [1 ]
Wang, Hu [1 ]
Chai, Yingjie [1 ]
Jin, Yaxue [1 ,2 ]
Qi, Hongji [1 ]
Shao, Jianda [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Key Lab Mat High Power Laser, Shanghai 201800, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] ShanghaiTech Univ, Shanghai 201210, Peoples R China
来源：
APPLIED SURFACE SCIENCE | 2018年 / 447卷
基金：
中国国家自然科学基金;
关键词：
GLAD; Annealing treatment; Electrochromic property; Tunable angular selectivity; NANOSTRUCTURED TUNGSTEN; OPTICAL-PROPERTIES; DEPOSITION; MORPHOLOGY;
D O I：
10.1016/j.apsusc.2018.03.248
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
WO3 thin films fabricated by glancing angle deposition (GLAD) are proposed as excellent electrochromic coatings with favorable ion diffusion. A similar to 500-nm film prepared by GLAD had a relatively large transmittance modulation. The crystallization structure, surface morphology, chemical state, optical and electrochromic properties of WO3 thin films were systematically characterized upon annealing treatment. Compared with annealed WO3 porous nanostructured films, the amorphous as-deposited films exhibited a high coloration efficiency and stable reversibility. Furthermore, the GLAD WO3 films exhibit the tunable angular selectivity under illumination with p-polarized light because of the birefringence, which could extend the application range of nanostructured films in the electrochromic field. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码：471 / 478
页数：8
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