A green and straightforward synthesis of 4′-substituted terpyridines

被引：68
|
作者：
Winter, Andreas
van den Berg, Antje M. J.
Hoogenboom, Richard
Kickelbick, Guido
Schubert, Ulrich S.
机构：
[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands
[2] Vienna Univ Technol, Inst Mat Chem, A-1060 Vienna, Austria
[3] Univ Munich, Ctr Nanosci, D-80333 Munich, Germany
来源：
SYNTHESIS-STUTTGART | 2006年 / 17期
关键词：
green chemistry; heterocycles; ligands; multicomponent reactions; terpyridines;
D O I：
10.1055/s-2006-942525
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A set of 4'-substituted 2,2': 6',2 ''-terpyri dines has been synthesized in a one-pot procedure under environmentally friendly reaction conditions using PEG and aqueous ammonia as solvents. This procedure features a short synthetic route, short reaction times, easy work-up, and good yields in comparison to conventional methods. The crystallographic data reveal the influence of the 4'-aryl substituent on the molecular structure and pi-stacking behavior of the respective terpyridines.
引用
收藏
页码：2873 / 2878
页数：6
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