Homochiral, helical metal-organic framework structures organized by strong, non-covalent π-π stacking interactions

被引：32

作者：

Reger, Daniel L. ^{[1
]}

Horger, Jacob ^{[1
]}

Smith, Mark D. ^{[1
]}

Long, Gary J. ^{[2
]}

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

[2] Univ Missouri, Missouri Univ Sci & Technol, Dept Chem, Rolla, MO 65409 USA

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 41期

基金：

美国国家科学基金会;

关键词：

1,8-NAPHTHALIMIDE SYNTHON; MOLECULES; MAGNETISM;

D O I：

10.1039/b916742k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new trifunctional ligand, L-ala, containing a carboxylate donor group, a homochiral center derived from L-alanine and a strong p-p stacking, 1,8-naphthalimide synthon, has been used to prepare the copper(II) complex [Cu(L-ala)(2)(4,4'-bipy)(H2O)(2)]center dot 4.25H(2)O that has a homochiral, helical, supramolecular metal-organic framework 3-D structure, organized in one dimension solely by strong non-covalent forces.

引用

页码：6219 / 6221

页数：3

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