Self-healing and shape-memory properties of polymeric materials cross-linked by hydrogen bonding and metal-ligand interactions

被引:31
|
作者
Kobayashi, Yuichiro [1 ]
Hirase, Tomohiro [1 ]
Takashima, Yoshinori [1 ,2 ]
Harada, Akira [3 ]
Yamaguchi, Hiroyasu [1 ]
机构
[1] Osaka Univ, Dept Macromol Sci, Grad Sch Sci, 1-1 Machikaneyama Cho, Toyonaka, Osaka 5600043, Japan
[2] Osaka Univ, Inst Adv Cocreat Studies, 1-1 Yamadaoka, Suita, Osaka 5650871, Japan
[3] Osaka Univ, Project Res Ctr Fundamental Sci, Grad Sch Sci, 1-1 Machikaneyama Cho, Toyonaka, Osaka 5600043, Japan
关键词
SUPRAMOLECULAR POLYMERS; COMPLEXES; MONOMERS; DRIVEN; BRIDGE;
D O I
10.1039/c9py00450e
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polymeric materials were prepared by cross-linking them with two independent non-covalent interactions, namely hydrogen bonding and metal-ligand interactions. The fracture energy of the resultant polymeric material is higher than that of the polymeric material without non-covalent interactions as well as that with one non-covalent interaction. Moreover, the prepared polymeric materials show self-healing and shape memory properties.
引用
收藏
页码:4519 / 4523
页数:5
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