Origin of acceptor diffusion into silicon substrate during GaN growth by metal organic chemical vapor deposition

This study investigated the change in carrier concentration near the surface of a silicon substrate during gallium nitride (GaN) growth with an aluminum nitride (AlN) buffer layer. It was observed that aluminum, gallium, and carbon diffused into the silicon substrate during the growth process and that the carrier concentration increased with increasing concentration of aluminum and gallium impurities. The gallium that diffused into the silicon substrate was identified as having originated from the gallium that decomposed on the reactor wall during the growth process and the gallium introduced onto the silicon substrate during GaN growth. In contrast, the amount of aluminum that diffused into the substrate was influenced by the duration of the trimethylaluminum (TMAI) flow: a long duration of the TMAI flow step before AlN growth led to a high aluminum concentration near the substrate surface. (C) 2019 The Japan Society of Applied Physics