Ferrocene substituted thiacyclophanes: Synthesis, electrochemistry and structure of 6-ethynylferrocene-2,11-dithia[3.3]orthocyclophane

被引：2
|
作者：
Tiburcio, Jorge [1 ,2 ]
Ugalde-Saldivar, Victor M. [1 ]
Loeb, Stephen J. [2 ]
Torrens, Hugo [1 ]
机构：
[1] Univ Nacl Autonoma Mexico, Fac Quim, Div Estudios Posgrado, Mexico City 04510, DF, Mexico
[2] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada
来源：
INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 11期
关键词：
Sulfur ligand; Cyclophanes; Ferrocene; Coupling reaction; X-ray crystal structure; Electrochemistry; METAL-COMPLEXES; PLATINUM; LIGANDS; CHROMIUM; BEHAVIOR; SPACERS; SULFUR;
D O I：
10.1016/j.ica.2009.05.029
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
6-Ethynylferrocene-2,11-dithia[3.3]orthocyclophane has been prepared by cross-coupling 6-bromo-2,11-dithia[3.3]orthocyclophane to ethynylferrocene under Sonogashira conditions. The dynamic structure in solution of this potential ligand has been examined by variable temperature NMR whereas its solid state structure has been determined by X-ray diffraction studies. The electrochemical parameters of this cyclophane have also been examined. (C) 2009 Elsevier B.V. All rights reserved.
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页码：4241 / 4245
页数：5
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