Oxidative degradation of dimethylsulfoxide by locally concentrated hydroxyl radicals in streamer corona discharge process

This study systematically investigates the characteristic degradation behaviors of dimethylsulfoxide (DMSO) by the streamer corona discharge process (SCDP) in water. The analysis of the oxidized intermediates of DMSO shows that hydroxyl radical ((OH)-O-center dot) is the main oxidant responsible for the degradation of DMSO in the SCDP. The various experiments on the degradation and mineralization of DMSO, and the effect of the (OH)-O-center dot scavenger suggest that the SCDP produces locally concentrated (center dot)OHs in and around the plasma channel. This explanation was also supported by the formation of H2O2 and the effect of the (OH)-O-center dot scavenger on the H2O2 production rate in the SCDP. Based on the kinetic data for the degradation of DMSO and the production of H2O2 in the SCDP, the volume of the active region in which the (center dot)OHs are concentrated, and the effective concentration of (OH)-O-center dot in that region were estimated to be 0.21 mu l and 5.0 x 10(-3) M, respectively. This level of (OH)-O-center dot concentration in the SCDP is approximately 10(7)-10(9) times higher than that generated in ordinary advanced oxidation processes using (OH)-O-center dot. The ramifications of the results obtained in this study on successful water treatment using the SCDP are also discussed. (c) 2006 Elsevier Ltd. All rights reserved.