Selective hydrogenation of cinnamaldehyde over carbon nanotube supported Pd-Ru catalyst

被引：41
|
作者：
Qiu, Jieshan
Zhang, Hongzhe
Wang, Xiuna
Han, Hongmei
Liang, Changhai
Li, Can
机构：
[1] Dalian Univ Technol, Sch Chem Engn, Ctr Nanomat & Sci,Carbon Res Lab, State Key Lab Fine Chem, Dalian 116012, Peoples R China
[2] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian, Peoples R China
[3] Ruhr Univ Bochum, Lab Ind Chem, D-44780 Bochum, Germany
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 2006年 / 88卷 / 02期
基金：
中国国家自然科学基金;
关键词：
carbon nanotubes; hydrogenation of cinnamaldehyde; palladium and ruthenium;
D O I：
10.1007/s11144-006-0061-z
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Carbon nanotube supported Pd, Ru and Pd-Ru catalysts have been prepared and tested with the hydrogenation of cinnamaldehyde as a probe reaction. It has been found that the cinnamaldehyde conversion and the selectivity towards the hydrogenation of C=O bond over Pd-Ru/PCNT catalyst could reach 56.6% and 79.1%, respectively, at 120 degrees C and 5.0 MPa, which is better than Pd/PCNT and Ru/PCNT catalysts under the same reaction conditions. It is assumed that the better performance of Pd-Ru/PCNT catalyst for cinnamaldehyde hydrogenation may be due to the synergic effect of Pd and Ru metals or the promoting effect of Ru metal.
引用
收藏
页码：269 / 275
页数：7
相关论文
共 50 条
  • [1] Selective hydrogenation of cinnamaldehyde over carbon nanotube supported pd-ru catalyst
    Jieshan Qiu
    Hongzhe Zhang
    Xiuna Wang
    Hongmei Han
    Changhai Liang
    Can Li
    [J]. Reaction Kinetics and Catalysis Letters, 2006, 88 : 269 - 276
  • [2] Pd-Ru/TiO2 catalyst - an active and selective catalyst for furfural hydrogenation
    Aldosari, Obaid F.
    Iqbal, Sarwat
    Miedziak, Peter J.
    Brett, Gemma L.
    Jones, Daniel R.
    Liu, Xi
    Edwards, Jennifer K.
    Morgan, David J.
    Knight, David K.
    Hutchings, Graham J.
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (01) : 234 - 242
  • [3] Selective hydrogenation of dehydrolinalool and dehydroisophytol in a liquid film moving over Pd-Ru foil
    Maganyuk, AP
    Gizhevskii, SF
    Gryaznov, VM
    [J]. ZHURNAL FIZICHESKOI KHIMII, 1998, 72 (08): : 1390 - 1393
  • [4] HYDROGENATION OF CINNAMALDEHYDE AND CITRAL OVER RU SUPPORTED CATALYSTS
    GALVAGNO, S
    MILONE, C
    NERI, G
    DONATO, A
    PIETROPAOLO, R
    [J]. HETEROGENEOUS CATALYSIS AND FINE CHEMICALS III, 1993, 78 : 163 - 170
  • [5] Poison Tolerance to the Selective Hydrogenation of Cinnamaldehyde in Water over an Ordered Mesoporous Carbonaceous Composite Supported Pd Catalyst
    Chen, Shangjun
    Meng, Li
    Chen, Bingxu
    Chen, Wenyao
    Duan, Xuezhi
    Huang, Xing
    Zhang, Bingsen
    Fu, Haibin
    Wan, Ying
    [J]. ACS CATALYSIS, 2017, 7 (03): : 2074 - 2087
  • [6] Selective hydrogenation of cinnamaldehyde over reduced graphene oxide supported Pt catalyst
    Shi, Juanjuan
    Nie, Renfeng
    Chen, Ping
    Hou, Zhaoyin
    [J]. CATALYSIS COMMUNICATIONS, 2013, 41 : 101 - 105
  • [7] Catalyst activity of carbon nanotube supported Pd catalysts for the hydrogenation of nitroarenes
    Kim, Ji Dang
    Choi, Myong Yong
    Choi, Hyun Chul
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2016, 173 : 404 - 411
  • [8] Selective hydrogenation of cinnamaldehyde to cinnamyl alcohol over mesoporous carbon supported Fe and Zn promoted Pt catalyst
    Mahata, Nagendranath
    Goncalves, Filomena
    Pereira, Manuel Fernando R.
    Figueiredo, Jose Luis
    [J]. APPLIED CATALYSIS A-GENERAL, 2008, 339 (02) : 159 - 168
  • [9] Tunable Selective Hydrogenation of Cinnamaldehyde by Capped Pt/Pd Nanoparticles Supported on Carbon Nanotubes
    Zhang, Minghui
    Wang, Tengda
    Zhang, Mingwei
    Wang, Qingfa
    Wang, Li
    Zhang, Xiangwen
    Li, Guozhu
    [J]. CHEMISTRYSELECT, 2022, 7 (15):
  • [10] Pd nanoparticles supported on ZIF-8 as an efficient heterogeneous catalyst for the selective hydrogenation of cinnamaldehyde
    Zhao, Yuan
    Liu, Mingming
    Fan, Binbin
    Chen, Yanfeng
    Lv, Wenmiao
    Lu, Ningyue
    Li, Ruifeng
    [J]. CATALYSIS COMMUNICATIONS, 2014, 57 : 119 - 123
12345