In this study, the removal of Malachite Green synthetic dye from aqueous environment was investigated using Sparus aurata as a source of fish bone. The removal efficiency of the adsorbent was investigated as a function of time and dye concentration via batch method at room temperature. The correlation coefficient values indicate that the data fit the Freundlich Isotherm (R-2= 0,9861) better than the Langmuir Isotherm (R-2=0,3695). The thermodynamic and reaction kinetic of Malachite Green from the aqueous solution were determined and correlated to pseudo-second order kinetic models and the experimental data revealed that pseudo-second order kinetic model is available to experimental data. Gibbs free energy value was found to be -1.308 kJ/mol and indicating the spontaneity of the system. Thermodynamic parameters exhibited that the adsorption process was spontenous (Delta G<O). According to the experimental results, the Sparus aurata bone can be used as an appropriate adsorbent for the removal of Malachite Green synthetic dye.
机构:
Department of Environmental Science, School of Sciences, Gujarat University, Ahmedabad, 380 009, GujaratDepartment of Environmental Science, School of Sciences, Gujarat University, Ahmedabad, 380 009, Gujarat
Raval N.P.
Shah P.U.
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Department of Environmental Science, School of Sciences, Gujarat University, Ahmedabad, 380 009, GujaratDepartment of Environmental Science, School of Sciences, Gujarat University, Ahmedabad, 380 009, Gujarat
Shah P.U.
Shah N.K.
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Department of Chemistry, School of Sciences, Gujarat University, Ahmedabad, 380 009, GujaratDepartment of Environmental Science, School of Sciences, Gujarat University, Ahmedabad, 380 009, Gujarat
机构:
Banaras Hindu Univ, Fac Sci, Dept Chem, Varanasi 221005, Uttar Pradesh, IndiaBanaras Hindu Univ, Fac Sci, Dept Chem, Varanasi 221005, Uttar Pradesh, India
Khattri, S. D.
Singh, M. K.
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Ideal Inst Technol, Dept Chem, Ghaziabad, UP, IndiaBanaras Hindu Univ, Fac Sci, Dept Chem, Varanasi 221005, Uttar Pradesh, India
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King Abdulaziz Univ, Fac Sci, Chem Dept, POB 80203, Jeddah 21413, Saudi ArabiaKing Abdulaziz Univ, Fac Sci, Chem Dept, POB 80203, Jeddah 21413, Saudi Arabia