Calorimetric and phase diagram studies of the Ga-In-Zn system

被引:6
|
作者
Kulawik, Sebastian [1 ]
Gierlotka, Wojciech [2 ]
Debski, Adam [3 ]
Gasior, Wladyslaw [3 ]
Zajaczkowski, Andrzej [1 ]
机构
[1] Inst Nonferrous Met, Lukasiewicz Res Network, 5 Sowinskiego St, PL-44100 Gliwice, Poland
[2] Natl Dong Hwa Univ, Dept Mat Sci & Engn, Hualien, Taiwan
[3] Polish Acad Sci, Inst Met & Mat Sci, 25 Reymonta St, PL-30059 Krakow, Poland
关键词
Ga-In-Zn alloys; Mixing enthalpy; Calorimetry; Thermodynamic modelling; GALLIUM-INDIUM; THERMODYNAMIC PROPERTIES; LIQUID ALLOYS; SN-ZN; ENTHALPY;
D O I
10.1016/j.molliq.2020.115114
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Partial and integral enthalpies of mixing of liquid Ga-In-Zn alloys at a temperature of 720 K were measured by high-temperature drop calorimetry. Calorimetric measurements were performed along four intersections as follows: x(Ga)/x(Zn) = 3/1, x(Ga)/x(Zn) = 1/1, x(Ga)/x(Zn) = 1/3 and x(Ga)/x(Zn) = 1/3. Based on obtained thermodynamic results and those available in the literature the thermodynamic optimization was done using Thermo-Calc software. Next, the phase equilibria in the binary and ternary systems were calculated and the results were compared with those obtained using different experimental techniques. (C) 2020 Published by Elsevier B.V.
引用
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页数:7
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