Crystal structure and magnetic properties of two bimetallic chain compounds

被引：0

作者：

Liu, Xue-Ying ^{[1
]}

Wang, Yi-Jun ^{[2
]}

Jin, Kai-Hang ^{[2
]}

Tong, Yu-Zhang ^{[2
]}

Yang, Chun ^{[1
]}

Wang, Qing-Lun ^{[2
]}

机构：

[1] Hebei Univ Technol, Sch Chem Engn & Technol, Tianjin 300130, Peoples R China

[2] Nankai Univ, Minist Educ, Key Lab Adv Energy Mat Chem, Coll Chem, Tianjin 300071, Peoples R China

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2020年 / 67卷 / 01期

基金：

中国国家自然科学基金;

关键词：

bimetallic complex; crystal structure; magnetic chain compound; magnetic property; COMPLEXES; MN; BEHAVIOR; NI;

D O I：

10.1002/jccs.201900175

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two bimetallic magnetic chain compounds of {[Mn(dpop)(H2O)][Mn(dpop)][Fe[CN](6)]center dot 8.5H(2)O center dot 0.5DMSO}(n) (1) and {[Mn(dpop)][Ni[CN](4)]}(n) (2) (dpop = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-[12.3.1]-octadeca-1(18),2,12,14,16-pentaene) have been synthesized and characterized by single-crystal X-ray diffraction and magnetic measurements. Both complexes have cyano-bridged chain structures, in which complex 1 is a zigzag chain, while complex 2 is nearly a straight line. The magnetic susceptibility results indicate that there is a weak ferromagnetic interaction between manganese (II) ions in complex 1, whereas the interaction is antiferromagnetic in complex 2.

引用

页码：103 / 108

页数：6

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