Synthesis and Spectral Properties of Low-Symmetry Phenoxy(chloro) and Phenylsulfanyl(chloro) Substituted Phthalocyanines

被引：3
|
作者：
Koptyaev, Andrey I. [1 ]
Galanin, Nikolay E. [1 ]
Shaposhnikov, Gennady P. [1 ]
机构：
[1] Ivanovo State Univ Chem & Technol, Ivanovo 153000, Russia
来源：
MACROHETEROCYCLES | 2015年 / 8卷 / 02期
基金：
俄罗斯基础研究基金会;
关键词：
Low-symmetry phthalocyanines; synthesis; spectral properties; UNSYMMETRICAL PORPHYRAZINES; PHOTOPHYSICAL PROPERTIES; PHTHALONITRILES;
D O I：
10.6060/mhc140925g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Low-symmetry phthalocyanines of the A(3)B, AABB and ABAB types were synthesized by mixed condensation of 4,5-diphenoxyphthalonitrile or 4,5-bis(phenylsulfanyl)phthalonitrile (components A) with tetrachlorophthalonitrile (component B). The compounds are isolated and purified by column chromatography. The composition and structure of the phthalocyanines were confirmed by elemental analysis, mass spectrometry, NMR and UV-Vis spectroscopy. On the basis of the UV-Vis and NMR spectroscopic data, strong aggregation of these compounds in solutions of polar and non-polar solvents was demonstrated.
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页码：156 / 161
页数：6
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