Soy polyol-based polyurethane modified by raw and silylated palygorskite

被引:24
|
作者
Wang, Chengshuang [1 ]
Ding, Liang [1 ]
Wu, Qisheng [1 ]
Liu, Fang [1 ]
Wei, Jun [1 ]
Lu, Rong [1 ]
Xie, Hongfeng [2 ]
Cheng, Rongshi [2 ,3 ]
机构
[1] Yancheng Inst Technol, Sch Mat Engn, Yancheng 224051, Peoples R China
[2] Nanjing Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab High Performance Polymer Mat & Technol, Nanjing 210093, Jiangsu, Peoples R China
[3] S China Univ Technol, Coll Mat Sci & Engn, Guangzhou 510641, Guangdong, Peoples R China
关键词
Polyurethane; Soy polyol; Palygorskite; Nanocomposites; EPOXIDIZED SOYBEAN OIL; THERMAL-STABILITY; SILICATE NANOCOMPOSITES; POLYMER; STRENGTH;
D O I
10.1016/j.indcrop.2014.03.025
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
In this study, we investigated the structure and loading effects of raw and silylated palygorskite (R-PA and S-PA) on the properties of soy polyol-derived polyurethane (PU) nanocomposites. Scanning electron microscope demonstrated that relatively homogeneous dispersion of both the R-PA and S-PA in the PU matrix. Dynamic mechanical analysis confirmed that both the PA could significantly improve the storage modulus and the glass transition temperature of PU nanocomposites, along with an intensified effect with the increase of PA loading. Tensile tests showed that both the PA has a prominent reinforcement effect on PU. Besides, we found that S-PA could slightly improve the thermal stability of PU nanocomposites, different from the case of the R-PA. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:29 / 34
页数:6
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