From Onsager to mixed ionic electronic conductors

被引：6

作者：

Lee, Taewon ^{[1
]}

Kim, Hong-Seok ^{[1
]}

Yoo, Han-Ill ^{[1
]}

机构：

[1] Seoul Natl Univ, Dept Mat Sci & Engn, WCU Hybrid Mat Program, Seoul 151744, South Korea

来源：

SOLID STATE IONICS | 2014年 / 262卷

基金：

新加坡国家研究基金会;

关键词：

Mixed ionic electronic conductors; Transport properties; Onsager coefficients; Semi-blocking cells; Ionic probes; Thermopower; TRANSPORT; FLOWS;

D O I：

10.1016/j.ssi.2013.10.048

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We propose to represent or document all the isothermal and nonisothermal mass/charge transport properties of mixed ionic electronic conductor compounds in terms of a simple Onsager transport coefficient matrix. To this end, the general equations of motion for mobile ions and electrons are formulated, complying with the irreversible thermodynamic rules, in terms of experimentally operable forces, and the measurement principles of the Onsager matrix are introduced on the basis of the chemical polarization in isothermal semi-blocking and nonisothermal complete-blocking conditions. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：2 / 8

页数：7