XPS study of oxygen adsorption on supported silver: Effect of particle size

被引：60
|
作者：
Bukhtiyarov, VI
Carley, AF
Dollard, LA
Roberts, MW
机构：
[1] BORESKOV INST CATALYSIS, NOVOSIBIRSK 630090, RUSSIA
[2] UNIV WALES COLL CARDIFF, DEPT CHEM, CARDIFF CF1 3TB, S GLAM, WALES
来源：
SURFACE SCIENCE | 1997年 / 381卷 / 2-3期
关键词：
carbon; chemisorption; clusters; oxygen; silver; soft x-ray photoelectron spectroscopy;
D O I：
10.1016/S0039-6028(97)00057-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The suggestion that two types of oxygen species are necessary for ethylene epoxidation is investigated using a model carbon-supported silver catalyst. It is established that the relative populations of the nucleophilic and electrophilic oxygen species are strongly dependent on silver particle size, the nucleophilic oxygen only being observed for cluster sizes greater than 300 Angstrom. The observation that the two types of oxygen only co-exist on large silver particles is consistent with reported epoxidation rates for silver catalysts. (C) 1997 Elsevier Science B.V.
引用
收藏
页码：L605 / L608
页数：4
相关论文
共 50 条
  • [1] XPS STUDY OF ADSORPTION OF OXYGEN ON SILVER
    Dong Shuzhong
    Bao Xinhe
    Deng Jingfa
    ACTA PHYSICO-CHIMICA SINICA, 1986, 2 (01) : 1 - 5
  • [2] XPS study of the size effect in ethene epoxidation on supported silver catalysts
    Bukhtiyarov, VI
    Prosvirin, IP
    Kvon, RI
    Goncharova, SN
    Balzhinimaev, BS
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1997, 93 (13): : 2323 - 2329
  • [3] The combined application of XPS and TPD to study of oxygen adsorption on graphite-supported silver clusters
    Bukhtiyarov, VI
    Kaichev, VV
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 158 (01) : 167 - 172
  • [4] OBSERVATION BY XPS AND EXAFS OF A CRYSTALLITE SIZE EFFECT IN ADSORPTION OF OXYGEN ON PT
    ROSS, PN
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1978, 125 (08) : C365 - C366
  • [5] AN XPS STUDY OF THE ADSORPTION OF OXYGEN ON SILVER AND PLATINUM SURFACES COVERED WITH POTASSIUM OR CESIUM
    AYYOOB, M
    HEGDE, MS
    SURFACE SCIENCE, 1983, 133 (2-3) : 516 - 532
  • [6] An XPS and STM study of the size effect in NO adsorption on gold nanoparticles
    Bukhtiyarov, A. V.
    Kvon, R. I.
    Nartova, A. V.
    Bukhtiyarov, V. I.
    RUSSIAN CHEMICAL BULLETIN, 2011, 60 (10) : 1977 - 1984
  • [7] An XPS and STM study of the size effect in NO adsorption on gold nanoparticles
    A. V. Bukhtiyarov
    R. I. Kvon
    A. V. Nartova
    V. I. Bukhtiyarov
    Russian Chemical Bulletin, 2011, 60 : 1977 - 1984
  • [8] XPS and UPS study of oxygen states on silver
    Boronin, AI
    Koscheev, SV
    Zhidomirov, GM
    JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1998, 96 (1-3) : 43 - 51
  • [9] XPS study of the surface properties and Ni particle size determination of Ni-supported catalysts
    Tarditi, Ana M.
    Barroso, Noelia
    Galetti, Agustin E.
    Arrua, Luis A.
    Cornaglia, Laura
    Abello, Maria C.
    SURFACE AND INTERFACE ANALYSIS, 2014, 46 (08) : 521 - 529
  • [10] In situ UV-vis studies of the effect of particle size on the epoxidation of ethylene and propylene on supported silver catalysts with molecular oxygen
    Lu, JQ
    Bravo-Suárez, JJ
    Takahashi, A
    Haruta, M
    Oyama, ST
    JOURNAL OF CATALYSIS, 2005, 232 (01) : 85 - 95
12345