Triterpenoid saponins containing an acetylated branched D-fucosyl residue from Quillaja saponaria Molina

被引:39
|
作者
Guo, SJ
Falk, E
Kenne, L
Rönnberg, B
Sundquist, BG
机构
[1] Swedish Univ Agr Sci, Dept Chem, SE-75007 Uppsala, Sweden
[2] Iscotec AB, SE-75183 Uppsala, Sweden
关键词
Quillaja saponaria Molina; structural analysis; saponins; quillaic acid; acetyl group;
D O I
10.1016/S0031-9422(99)00422-7
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Seven novel saponins were isolated from a bark extract of Quillaja saponaria Molina, the compounds were characterized, using mainly NMR spectroscopy, mass spectrometry and chemical methods, as quillaic acid substituted at C-3 with oligosaccharides consisting of various compositions of D-glucuronic acid D-galactose, D-xylose, and L-rhamnose and at C-28 with complex oligosaccharide structures consisting of various compositions of D-xylose, L-rhamnose, D-apiose and a branched 4-O-acetyl-D-fucose residue. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:861 / 868
页数:8
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