X-ray Crystallography Analysis of Complexes Synthesized with Tris(2-pyridylmethyl)amine: A Laboratory Experiment for Undergraduate Students Integrating Interdisciplinary Concepts and Techniques

被引：14
|
作者：
Bazley, Isabel J. [1 ]
Erie, Ellen A. [1 ]
Feiereisel, Garrett M. [1 ]
Lewarne, Christopher J. [1 ]
Peterson, Jack M. [1 ]
Sandquist, Katherine L. [1 ]
Oshin, Kayode D. [1 ]
Zeller, Matthias [2 ]
机构：
[1] Creighton Univ, Dept Chem, Omaha, NE 68102 USA
[2] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA
来源：
JOURNAL OF CHEMICAL EDUCATION | 2018年 / 95卷 / 05期
基金：
美国国家科学基金会;
关键词：
Second-Year Undergraduate; Upper-Division Undergraduate; Organic Chemistry; Inorganic Chemistry; Laboratory Instruction; Hand-On Learning/Manipulatives; NMR Spectroscopy; Synthesis; Crystals/Crystallography; LIGANDS;
D O I：
10.1021/acs.jchemed.7b00685
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An integrated laboratory experiment applying concepts and techniques from organic chemistry, inorganic chemistry, and instrumental analysis is presented for use in the undergraduate curriculum. This experiment highlights the synthesis, characterization, and use of tris(2-pyridylmethyl)amine (TPMA) to make complexes with different metal salts. It incorporates laboratory practices such as literature searches, multistep synthesis, reaction mechanisms, NMR spectroscopy, and X-ray crystallography.
引用
收藏
页码：876 / 881
页数：6
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