Solution Thermodynamics of Benzotriazole in Different Pure Solvents

被引：13

作者：

Luan, Yanan ^{[1
,2
]}

Li, Jing ^{[1
]}

Kaliwanda, Musika ^{[1
]}

Wang, Na ^{[1
]}

Chen, Kui ^{[1
]}

Li, Xin ^{[1
]}

Su, Weiyi ^{[3
]}

Hao, Hongxun ^{[1
,2
]}

机构：

[1] Tianjin Univ, Sch Chem Engn & Technol, Natl Engn Res Ctr Ind Crystallizat Technol, Tianjin 300072, Peoples R China

[2] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China

[3] Hebei Univ Technol, Sch Chem Engn, Tianjin 300130, Peoples R China

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2018年 / 63卷 / 05期

基金：

中国国家自然科学基金;

关键词：

VAPOR-LIQUID-EQUILIBRIUM; EXCESS MOLAR VOLUMES; BINARY-MIXTURES; FREE-ENERGY; 20; MPA; SOLUBILITY; PRESSURES; DENSITIES; METHANOL; ETHANOL;

D O I：

10.1021/acs.jced.7b01085

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Solubility data of benzotriazole (BTA) in 14 solvents were measured by a static gravimetric method from 268.15 to 303.15 K. The results illustrated that the solubility of BTA in N,N-dimethylacetamide is the highest whereas that in 1,2-dichloroethane is the lowest in all the tested solvents. And the values of solubility increase with increasing of temperature. Additionally, the modified Apelblat equation, the lambda h equation, the NRTL model, and the Wilson model were employed to correlate the experimental solubility data. It was found that all the selected thermodynamic models could give satisfactory correlation results. Furthermore, the thermodynamic properties of BTA during the dissolving process, including the enthalpy, the Gibbs energy, and the entropy, were also calculated and analyzed.

引用

页码：1546 / 1555

页数：10

共 50 条

[1] Comment on "Solution Thermodynamics of Benzotriazole in Different Pure Solvents"
Acree, William E., Jr.
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2018, 63 (05): : 1844 - 1845
[2] Solubility and Solution Thermodynamics of Diphenoxylate in Different Pure Solvents
Qing, Xue-Yan
Fu, Hua-Lin
Shu, Gang
Liu, Meng-Jiao
Zhou, Jian-Yu
Wu, Wen-Bin
Zhang, Yan-Li
Zhou, Jun-Jie
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2015, 60 (06): : 1629 - 1633
[3] Solution thermodynamics of valnemulin hydrogen fumarate in different pure solvents
Ouyang, Jinbo
Wang, Jingkang
Huang, Xin
Bao, Ying
Wang, Yongli
Yin, Qiuxiang
Liu, Ailing
Li, Xudong
Hao, Hongxun
JOURNAL OF CHEMICAL THERMODYNAMICS, 2015, 91 : 73 - 79
[4] Determination and correlation of solubility and solution thermodynamics of ethenzamide in different pure solvents
Tong, Yao
Wang, Zhanzhong
Yang, Entao
Pan, Bochen
Jiang, Jun
Dang, Leping
Wei, Hongyuan
FLUID PHASE EQUILIBRIA, 2016, 427 : 549 - 556
[5] Determination and correlation of solubility and solution thermodynamics of saccharin in different pure solvents
Tong, Yao
Zhai, Shangru
Wang, Kai
Li, Hongsheng
An, Qingda
JOURNAL OF CHEMICAL THERMODYNAMICS, 2019, 133 : 70 - 78
[6] Solubility and Solution Thermodynamics of Betaine in Different Pure Solvents and Binary Mixtures
Wang, Shui
Qin, Liying
Zhou, Zhimao
Wang, Jidong
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2012, 57 (08): : 2128 - 2135
[7] Determination and correlation of solubility and solution thermodynamics of coumarin in different pure solvents
Huang, Xin
Wang, Jingkang
Hao, Hongxun
Ouyang, Jinbo
Gao, Yuan
Bao, Ying
Wang, Yongli
Yin, Qiuxiang
FLUID PHASE EQUILIBRIA, 2015, 394 : 148 - 155
[8] Solubility, Density and Solution Thermodynamics of NaI in Different Pure Solvents and Binary Mixtures
Pawar, Ramesh R.
Aher, Chandrakant S.
Pagar, Jitendra D.
Nikam, Sonali L.
Hasan, Mehdi
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2012, 57 (12): : 3563 - 3572
[9] Determination and correlation of solubility and solution thermodynamics of musk xylene in different pure solvents
Zou, Zongpeng
Yu, Yi
Fang, Xin
Liu, Guoji
Xu, Li
JOURNAL OF CHEMICAL THERMODYNAMICS, 2019, 135 : 205 - 214
[10] Comment on "Determination and correlation of solubility and solution thermodynamics of ethenzamide in different pure solvents"
Zhang, Tong-wei
Liu, Yong-zheng
Li, Yong-xiang
Li, Zi-yang
FLUID PHASE EQUILIBRIA, 2021, 538

← 1 2 3 4 5 →