Asymmetric allylic alkylation of cycloalkenediol diacetates using a chiral phosphine ligand bearing a carboxyl group

被引：18

作者：

Okauchi, T ^{[1
]}

Fujita, K ^{[1
]}

Ohtaguro, T ^{[1
]}

Ohshima, S ^{[1
]}

Minami, T ^{[1
]}

机构：

[1] Kyushu Inst Technol, Dept Appl Chem, Kitakyushu, Fukuoka 8048550, Japan

来源：

TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 06期

关键词：

D O I：

10.1016/S0957-4166(00)00080-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Asymmetric induction in the allylic alkylation of cycloalkenediol diacetates was performed using a chiral alkylphosphine ligand bearing a carboxyl group, 3-(diphenylphosphino)butanoic acid. An increase in enantiomeric excess of the monoalkylated products of cis-cycloalkenediol diacetates was observed through a sequential asymmetric allylic alkylation-kinetic resolution process. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：1397 / 1403

页数：7

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