Ester-Directed Selective Olefination of Acrylates by Rhodium Catalysis

被引：47
|
作者：
Feng, Ruokun [1 ]
Yu, Wenlong [1 ]
Wang, Kai [1 ]
Liu, Zhanxiang [1 ]
Zhang, Yuhong [1 ,2 ]
机构：
[1] Zhejiang Univ, Dept Chem, ZJU NHU United R&D Ctr, Hangzhou 310027, Peoples R China
[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2014年 / 356卷 / 07期
关键词：
C-H bond activation; ester group directed olefination; oxidative coupling; rhodium-catalyzed olefination; substituted; 1; 3-dienes; C-H BONDS; CROSS-COUPLING REACTION; ORTHO-ARYLATION; AROMATIC ESTERS; ALKENYLATION; ARENES; FUNCTIONALIZATION; EFFICIENT; ACCESS; ACID;
D O I：
10.1002/adsc.201300944
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Ester-directed olefination of acrylates via rhodium(III)-catalysis was developed. Various alkenes were reacted with acrylates to give the desired products in high stereoselectivity. Mechanistic investigations revealed that ester-directed CH bond activation was the key step to this reaction.
引用
收藏
页码：1501 / 1508
页数：8
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