Electrocatalytic oxidative Z/E isomerization of a stilbene favoured by the presence of an electroactive persistent radical

被引：2

作者：

Mayorga-Burrezo, Paula ^{[1
]}

Sporer, Christian ^{[1
]}

de Sousa, J. Alejandro ^{[1
,2
]}

Capra, Nicola ^{[1
]}

Wurst, Klaus ^{[3
]}

Crivillers, Nuria ^{[1
]}

Veciana, Jaume ^{[1
]}

Rovira, Concepcio ^{[1
]}

机构：

[1] Inst Ciencia Mat Barcelona ICMAB CSIC CIBER BBN, Dept Mol Nanosci & Organ Mat, Campus Univ Bellaterra, E-08193 Barcelona, Spain

[2] Univ Los Andes, Fac Ciencia, Dept Quim, Lab Electroquim, Merida 5101, Venezuela

[3] Univ Innsbruck, Inst Gen Inorgan & Theoret Chem, Ctr Chem & Biomed, Innrain 80-82, A-6020 Innsbruck, Austria

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 91期

关键词：

OPTICAL-PROPERTIES; PHOTOISOMERIZATION; CATIONS; MECHANISM; DYNAMICS;

D O I：

10.1039/d0cc04973e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A push-pull-functionalized stilbene has been prepared, with an electroactive perchlorotriphenylmethyl (PTM) radical and dimethylamine units as electron-withdrawing and -donating moieties, respectively, showing an electrocatalytic redox-induced Z -> E isomerization where the open-shell nature of PTM plays a key role in the isomerization ocurrance.

引用

页码：14211 / 14214

页数：4

共 18 条

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