BiVO4 tubular structures: oxygen defect-rich and largely exposed reactive {010} facets synergistically boost photocatalytic water oxidation and the selective N=N coupling reaction of 5-amino-1H-tetrazole

被引：16

作者：

Hu, Jianqiang ^{[1
]}

He, Huichao ^{[2
]}

Zhou, Xin ^{[3
]}

Li, Zhaosheng ^{[1
,4
,5
]}

Shen, Qing ^{[6
]}

Luo, Wenjun ^{[5
]}

Alsaedi, Ahmed ^{[7
]}

Hayat, Tasawar ^{[7
,8
]}

Zhou, Yong ^{[1
,4
,9
]}

Zou, Zhigang ^{[1
,4
,5
,9
]}

机构：

[1] Nanjing Univ, Sch Phys, Collaborat Innovat Ctr Adv Microstruct, Natl Lab Solid State Microstruct, Nanjing 210093, Jiangsu, Peoples R China

[2] Southwest Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Environm Friendly Energy Mat, Mianyang 621010, Sichuan, Peoples R China

[3] Dalian Univ, Coll Environm & Chem Engn, Dalian 116622, Liaoning, Peoples R China

[4] Nanjing Univ, Key Lab Nano Technol, Nanjing 210093, Jiangsu, Peoples R China

[5] Nanjing Univ, Coll Engn & Appl Sci, Nanjing 210093, Jiangsu, Peoples R China

[6] Univ Electrocommun, Fac Informat & Engn, Tokyo 1828585, Japan

[7] King Abdulaziz Univ, Fac Sci, Jeddah 21589, Saudi Arabia

[8] Quaid I Azam Univ, Dept Math, Islamabad 45320, Pakistan

[9] Nanjing Univ, Kunshan Innovat Inst, Kunshan Sunlaite New Energy Co Ltd, Kunshan 215347, Jiangsu, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 39期

关键词：

NANOTUBES; NANOSHEETS; EXFOLIATION; MECHANISM; SALTS; OXIDE;

D O I：

10.1039/c9cc01290g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unprecedented, oxygen defect-rich, monoclinic BiVO4 nanotubes with largely exposed active {010} facets were successfully fabricated through a self-curling process of nascently generated ultrathin lamellar sheets, exhibiting impressive photocatalytic performance for both water oxidation and the selective NQN coupling reaction of 5-amino-1H-tetrazole into sodium 5,5-azotetrazolate, with more than an order of magnitude enhancement relative to bulk materials.

引用

页码：5635 / 5638

页数：4