Promoting Effect of Lewis Acid on the Olefin Hydroesterification Catalyzed by Triphenylphosphine-Palladium Complex

被引:22
|
作者
Yang, Jing [1 ]
Yuan, Youzhu [1 ]
机构
[1] Xiamen Univ, Dept Chem,Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Natl Engn Lab Green Chem Prod Alcohols Ethers Est, Xiamen 361005, Peoples R China
关键词
Hydroesterification; PPh3-Pd complex; Lewis acid; Promoter; CARBON-MONOXIDE; METHOXYCARBONYLATION; ALKENES; CARBONYLATION; INSERTION; STYRENE;
D O I
10.1007/s10562-009-0007-y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A number of Lewis acids obtained by a reaction of metal oxides with Bronsted acids such as para-toluenesulfonic acid (p-TsOH) and methanesulfonic acid (CH3SO3H) have been employed as promoter for styrene hydroesterification catalyzed by triphenylphosphine-palladium (PPh3-Pd) complex. The acidities of the Lewis acids were analyzed by potentiometric titration and the PPh3 consumption during the hydroesterification was characterized by P-31 NMR. The results indicated that the use of Lewis acid with apparent pH similar to p-TsOH can bring about a marked enhancement in the reaction rate and a significant depression in the PPh3 consumption. Such kind of Lewis acids may be more suitable as promoter for the olefin hydroesterification than the conventional Bronsted acids.
引用
收藏
页码:643 / 648
页数:6
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