Asymmetric aza-Diels-Alder reaction of Danishefsky's diene with imines in a chiral reaction medium

被引：33
|
作者：
Pegot, Bruce [1 ]
Van Buu, Olivier Nguyen [1 ]
Gori, Didier [1 ]
Vo-Thanh, Giang [1 ]
机构：
[1] Univ Paris 11, Lab Chim Procedes & Subst Nat, ICMMO, CNRS,UMR 8182, F-91405 Orsay, France
来源：
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 2卷
关键词：
D O I：
10.1186/1860-5397-2-18
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The asymmetric aza-Diels-Alder reaction of chiral imines with Danishefsky's diene in chiral ionic liquids provides the corresponding cycloadduct with moderate to high diastereoselectivity. The reaction has proved to perform better at room temperature in ionic liquids without either Lewis acid catalyst or organic solvent. Chiral ionic liquids are recycled while their efficiency is preserved.
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页数：5
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