Diaquabis(ethylenediamine)cadmium(II) bis(4-aminonaphthalene-1-sulfonate) dihydrate

被引:6
|
作者
Li, Ming-Tian
Wang, Cheng-Gang [1 ]
Fu, Xu-Cheng
机构
[1] Cent China Normal Univ, Dept Chem, Wuhan 430079, Hubei, Peoples R China
[2] W Anhui Univ, Dept Biol & Chem, Liu An 237000, Anhui, Peoples R China
关键词
D O I
10.1107/S0108270106029854
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the title compound, [Cd(C2H8N2)(2)(H2O)(2)](C10H8NO3S)(2)center dot-2H(2)O, the Cd-II atom, located on an inversion centre, has a distorted octahedral coordination geometry formed by two ethylenediamine and two water molecules. 4-Aminonaphthalene-1-sulfonate acts as a counter-ion to balance the charge, and two antiparallel anions showing strong pi-pi stacking interactions are linked by paired N-H center dot center dot center dot O(sulfonate) hydrogen bonds into an isolated R-2(2)(16) dimer. The crystal structure is stabilized by the pi-pi stacking interactions and hydrogen bonds.
引用
收藏
页码:M434 / M436
页数:3
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