Synthesis, Structure and Photoluminescent Properties of the 2D Coordination Polymers Based on Cu2Br2 Unit with Flexible Thioether

被引：0

作者：

Li Dong-Qing ^{[1
]}

Shi Wen-Juan ^{[2
]}

机构：

[1] Yulin Normal Univ, Dept Biol & Chem, Yulin 537000, Guangxi, Peoples R China

[2] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Surface Engn, Nanchang 330013, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 25卷 / 02期

关键词：

copper(I) coordination polymer; flexible thioether; crystal structure; photoluminescence; FRAMEWORK FORMATION; COMPLEXES; SOLVENTS;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A complex [Cu2Br2(L)(2)](n) (1) (L=bis(2-pyrimidinylthio)methane) has been synthesized and structurally characterized. Complex 1 contains dinuclear Cu2Br2 units, which are linked by ditopic L to form a 2D layer structure with a 36-membered macrometallocycle. The adjacent layers are further connected through interpyrimidyl rings C-H center dot center dot center dot N and pi-pi interactions to give rise to a three-dimensional supramolecular structure. Complex 1 also displays strong green solid-state photoluminescence, due to metal-to-ligand charge-transfer (MLCT) at room temperature. CCDC: 711434.

引用

页码：364 / 368

页数：5

共 16 条

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