A smarter approach to catalysts by design: Combining surface organometallic chemistry on oxide and metal gives selective catalysts for dehydrogenation of 2,3-dimethylbutane

被引：5

作者：

Rouge, Pascal ^{[1
]}

Garron, Anthony ^{[1
]}

Norsic, Sebastien ^{[1
]}

Larabi, Cherif ^{[1
]}

Merle, Nicolas ^{[2
]}

Delevoye, Laurent ^{[2
]}

Gauvin, Regis M. ^{[2
]}

Szeto, Kai C. ^{[1
]}

Taoufik, Mostafa ^{[1
]}

机构：

[1] Univ Lyon 1, Inst Chim Lyon, CPE Lyon, CNRS,UMR 5265,C2P2,LCOMS, Batiment 308 F 43 Blvd 11 Novembre 1918, F-69616 Villeurbanne, France

[2] Univ Lille, Univ Artois, Cent Lille, ENSCL,UMR 8181,UCCS, F-59000 Lille, France

来源：

MOLECULAR CATALYSIS | 2019年 / 471卷

关键词：

Li-functionalized gamma-alumina; Pt; PtSn; PtGe nanoparticles; 2,3-Dimethylbutene; Spectroscopic characterization; Continuous flow reactor; PT-SN/AL2O3; CATALYSTS; REFORMING CATALYSTS; PARTICLE-SIZE; N-BUTANE; PLATINUM; ISOBUTANE; ISOMERIZATION; SPECTROSCOPY; MECHANISMS; PT/AL2O3;

D O I：

10.1016/j.mcat.2019.04.011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

2,3-dimethylbutane is selectively converted into 2,3-dimethylbutenes at 500 degrees C under hydrogen or at 390 degrees C under nitrogen in the presence of bimetallic catalysts Pt-Sn/Li-Al2O3. The high stability of the catalyst along the reaction is obtained by selective modification of the Pt/Li-Al2O3 catalyst using Surface Organometallic Chemistry (SOMC).

引用

页码：21 / 26

页数：6

共 13 条

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