Bio-active synthesis of tin oxide nanoparticles using eggshell membrane for energy storage application

被引:32
|
作者
Selvakumari, J. Celina [1 ]
Nishanthi, S. T. [2 ]
Dhanalakshmi, J. [1 ]
Ahila, M. [1 ]
Padiyan, D. Pathinettam [1 ]
机构
[1] Manonmaniam Sundaranar Univ, Dept Phys, Tirunelveli 627012, Tamil Nadu, India
[2] CSIR Cent Electrochem Res Inst, Electrochem Power Sources Div, Karaikkudi 630006, Tamil Nadu, India
关键词
Eggshell membrane; Nanoparticles; Photoluminescence; Tin oxide; X-ray diffraction; Energy storage; PHOTOCATALYTIC ACTIVITY; SNO2; NANOPARTICLES; HYDROTHERMAL SYNTHESIS; RAMAN-SPECTRA; PHOTOLUMINESCENCE; PERFORMANCE; CARBON; SUPERCAPACITOR; DEGRADATION; REDUCTION;
D O I
10.1016/j.apsusc.2018.02.043
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nano-sized tin oxide (SnO2) particles were synthesized using eggshell membrane (ESM), a natural bio-waste from the chicken eggshell. The crystallization of SnO2 into the tetragonal structure was confirmed from powder X-ray diffraction and the crystallite size ranged from 13 to 40 nm. Various shapes including rod, hexagonal and spherical SnO2 nanoparticles were observed from the morphological studies. The electrochemical impedance study revealed a lower charge transfer resistance (R-ct) of 8.565 Omega and the presence of a constant phase element which arised due to surface roughness and porosity. Capacitive behavior seen in the cyclic voltammetry curve of the prepared SnO2 nanoparticles, find future applications in supercapacitors. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:530 / 537
页数:8
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