Hedgehog-like polycrystalline Si as anode material for high performance Li-ion battery

被引:0
|
作者
Zhang, Chunqian [1 ]
Li, Chuanbo [1 ]
Du, Feihu [2 ]
Wang, Kaixue [2 ]
Xue, Chunlai [1 ]
Cheng, Buwen [1 ]
Wang, Qiming [1 ]
机构
[1] Chinese Acad Sci, Inst Semicond, State Key Lab Integrated Optoelect, Beijing 100083, Peoples R China
[2] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China
基金
日本学术振兴会; 北京市自然科学基金; 中国国家自然科学基金;
关键词
SILICON ANODE; LITHIUM; PARTICLES;
D O I
10.1039/c4ra12760a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A hedgehog-like Si nanomaterial has been prepared by metal assisted chemical etchingmethod with polycrystalline Si powder as raw material and used as anode for lithium-ion batteries. The cycle stability and impedance are greatly enhanced compared with pristine silicon powder, and the Columbic efficiency (CE) keeps above 99.5% for up to 200+ cycles. The improved electrochemical characteristics are attributed to its volume buffering and effective conductance due to the unique structure, which combines nanowires on the surface and a core inside. The additives in electrolyte and suitable conductive materials help to stabilise the anode as well.
引用
收藏
页码:57083 / 57086
页数:4
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