Synthesis of 5-Hydroxymethylfurfural from Sucrose Catalyzed by Phosphotungstate

被引：4

作者：

Qiu, Guo ^{[1
]}

Wang, Xincheng ^{[2
]}

Huang, Chongpin ^{[1
]}

Zhang, Pu ^{[1
]}

Li, Yingxia ^{[1
]}

Chen, Biaohua ^{[1
]}

机构：

[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China

[2] Beijing Inst Petrochem Technol, Beijing Key Lab Fuels Cleaning & Adv Catalyt Emis, Beijing 102617, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 38卷 / 04期

基金：

中国国家自然科学基金;

关键词：

5-hydroxymethylfurfural; sucrose; phosphotungstate; CONVERSION; DEHYDRATION; ZEOLITES; FRUCTOSE; ACIDITY; BIOMASS;

D O I：

10.6023/cjoc201709007

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

5-Hydroxymethylfurfural (5-HMF) is one of the most important biomass-derived platform compounds and can be used to produce various chemicals. The synthesis of 5-hydroxymethylfurfural (5-HMF) from sucrose catalyzed by a variety of phosphotungstate (Nb0.6PW12O40, Sn0.75PW12O40, CrPW12O40, CePW12O40) has been studied, and the catalysts are characterized 12- 40, Sn by FTIR, XRD, UV-vis,TGA, NH3-TPD and NMR. The optimum yield of 5-HMF reached 62.54% with 99.3% conversion of sucrose, using Nb0.6PW12O40 in dimethyl sulfoxide (DMSO) at 80 degrees C under 0.1 MPa of N-2 with reaction time of 90 min. Moreover, Nb0.6PW12O40 could be reused five times without loss of activity, and the reaction mechanism was proposed. This study has reference significance for carbohydrate conversion to 5-HMF.

引用

页码：940 / 948

页数：9

共 30 条

[1] And F. S. A., 2007, IND ENG CHEM RES, V46, P7703
[2] And F. S. A., 2006, IND ENG CHEM RES, V45, P2163
[3] [Anonymous], 2015, THESIS
[4] [Anonymous], 2012, Master Thesis.
[5] [Anonymous], 2012, THESIS
[6] Porous nanomaterials as green catalyst for the conversion of biomass to bioenergy
Bhanja, Piyali
Bhaumik, Asim
[J]. FUEL, 2016, 185 : 432 - 441
[7] [曹小华 Cao Xiaohua], 2013, [功能材料, Journal of Functional Materials], V44, P1736
[8] Selective saccharides dehydration to 5-hydroxymethyl-2-furaldehyde by heterogeneous niobium catalysts
Carlini, C
Giuttari, M
Galletti, AMR
Sbrana, G
Armaroli, T
Busca, G
[J]. APPLIED CATALYSIS A-GENERAL, 1999, 183 (02) : 295 - 302
[9] Cooperative action of Bronsted and Lewis acid sites of niobium phosphate catalysts for cellobiose conversion in water
Carniti, Paolo
Gervasini, Antonella
Bossola, Filippo
Dal Santo, Vladimiro
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 193 : 93 - 102
[10] Synthesis of 5-hydroxymethylfurfural from fructose catalyzed by phosphotungstic acid
Gomes, Filipe N. D. C.
Mendes, Fabiana M. T.
Souza, Mariana M. V. M.
[J]. CATALYSIS TODAY, 2017, 279 : 296 - 304

← 1 2 3 →