A note on the Noyori model for chiral amplification in the aminoalcohol-catalyzed reaction of aldehydes with dialkylzinc

被引：0
|
作者：
Gutman, I [1 ]
机构：
[1] Univ Kragujevac, Fac Sci, YU-34000 Kragujevac, Yugoslavia
来源：
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY | 1999年 / 64卷 / 11期
关键词：
chiral stereoselection; chiral amplification; chiral catalysis; asymmetric synthesis;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Noyori model of chiral amplification in the alkylation of aldehydes by means of dialkylzinc, catalyzed by chiral aminoalcohols, is further elaborated. A direct, but approximate, relation is obtained between the enantiomeric excess of the catalyst added and the enantiomeric excess of the product.
引用
收藏
页码：681 / 684
页数：4
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