Improving the flame retardancy and mechanical properties of epoxy composites using flame retardants with red mud waste

被引:17
|
作者
Kusakli, Sefa [1 ]
Kocaman, Suheyla [2 ]
Ceyhan, Ayhan Abdullah [2 ]
Ahmetli, Gulnare [2 ]
机构
[1] Selcuk Univ, Dept Chem Engn, Fac Engn, Konya, Turkey
[2] Konya Tech Univ, Fac Engn & Nat Sci, Dept Chem Engn, Konya, Turkey
关键词
VINYL ACETATE COMPOSITES; THERMAL-DEGRADATION; ALUMINUM-HYDROXIDE; AMMONIUM POLYPHOSPHATE; SURFACE MODIFICATION; TRIHYDROXIDE;
D O I
10.1002/app.50106
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this study, a novel flame retardant ammonium tetrafluoroborate (ATFB) was successfully synthesized using boric acid (H3BO3) and ammonium hydrogen difluoride (NH4HF2) as the reactants. In addition to ATFB, aluminum hydroxide (Al(OH)(3)) was used as a flame retardant and red mud (RM) waste was used as a filler to prepare epoxy composite materials with enhanced flammability properties. The appropriate ratio of RM:ATFB:Al(OH)(3)both in terms of combustion and mechanical properties was found to be 15:10:5 wt%. The tensile strength of the composite in this ratio was obtained as 112 MPa, while the neat ER was 46 MPa. The burnout of the composite with the appropriate RM:ATFB:Al(OH)(3)ratio decreased in the first 10 seconds, and extinguished in 32 seconds. Moreover, the burned area of this composite was the smallest among all the others. The experimental and estimatedLOIvalues for this composite was found as 26 and 29, respectively.
引用
收藏
页数:15
相关论文
共 50 条
  • [1] Improvement of mechanical properties and flame retardancy of epoxy resin by phosphorylated cyclotriphosphazene hyperbranched polymeric flame retardants
    Cui, Jinfeng
    Yu, Hailong
    Li, Ting
    Zhu, Yingxue
    Zhu, Anjun
    Mao, Xin
    Qi, Chengxia
    Yang, Baoping
    Guo, Junhong
    Mu, Bo
    Tian, Li
    [J]. POLYMER, 2022, 256
  • [2] Improving processability and mechanical properties of epoxy resins with biobased flame retardants
    Gong, Yuning
    Zhang, Lanyue
    He, Jiahuan
    Liu, Baiyu
    Wang, Lu
    Ao, Yuhui
    Liu, Yu
    Shang, Lei
    [J]. POLYMER INTERNATIONAL, 2024, 73 (08) : 646 - 657
  • [3] Improving flame retardancy and mechanical properties of polyamide 6 induced by multiple reactions among flame retardants and matrix
    Sun, Jinhao
    Zhang, Di
    Yang, Yong
    Guo, Zhenghong
    Fang, Zhengping
    Chen, Peng
    Li, Juan
    [J]. REACTIVE & FUNCTIONAL POLYMERS, 2023, 187
  • [4] Effects of waste coffee grounds on the mechanical properties, flame retardancy and toxic gas production of epoxy composites
    Yang, Wenmu
    Chang, Wenkai
    Zhang, Jin
    Yeoh, Guan Heng
    Boyer, Cyrille
    Wang, Chun H.
    [J]. MATERIALS & DESIGN, 2022, 224
  • [5] Cyclotriphosphazene hyperbranched P/N/Si prepared flame retardants improve mechanical properties and flame retardancy of epoxy resins
    Yu, Hailong
    Tian, Li
    Li, Ting
    Zhu, Yingxue
    Zhu, Anjun
    Guo, Xiaoqian
    Liu, Kangli
    Yang, Baoping
    Guo, Junhong
    Mu, Bo
    Cui, Jinfeng
    [J]. POLYMERS FOR ADVANCED TECHNOLOGIES, 2022, 33 (10) : 3263 - 3278
  • [6] Preparation, flame retardancy, and mechanical properties of flame-retardant glass fibre reinforced epoxy composites
    Su, Liping
    Li, Zhinong
    Huang, Zhensheng
    Lai, Kaigong
    Zhang, Huagui
    Liu, Canpei
    Chen, Mingfeng
    Zhang, Xu
    [J]. PLASTICS RUBBER AND COMPOSITES, 2020, 49 (10) : 443 - 449
  • [7] Flame retardancy and Mechanical Properties of Ecofriendly Coated Hemp Fabrics/Epoxy Composites
    Bifulco, Aurelio
    Capasso, Agostino
    Durante, Massimo
    Piccolo, Alessandro
    Mazzei, Pierluigi
    Costantini, Aniello
    Silvestri, Brigida
    Pennetta, Miriam
    Malucelli, Giulio
    Branda, Francesco
    [J]. 9TH INTERNATIONAL CONFERENCE ON TIMES OF POLYMERS AND COMPOSITES: FROM AEROSPACE TO NANOTECHNOLOGY, 2018, 1981
  • [8] Multi-element hybrid flame retardants balance flame retardancy and mechanical performance of epoxy coatings
    Zhang, Li
    Xia, Yan
    Sun, Jinhao
    Guo, Zhenghong
    Fang, Zhengping
    Chen, Peng
    Li, Juan
    [J]. PROGRESS IN ORGANIC COATINGS, 2024, 188
  • [9] Polyurethane/Red Mud Composites with Flexibility, Stretchability, and Flame Retardancy for Grouting
    Zhang, Chunjing
    Shuai, Bo
    Zhang, Xuefeng
    Hu, Xinxin
    Zhang, Hui
    Jia, Yuanheng
    Yang, Zhengpeng
    Guan, Xuemao
    [J]. POLYMERS, 2018, 10 (08)
  • [10] Highly Efficient Composite Flame Retardants for Improving the Flame Retardancy, Thermal Stability, Smoke Suppression, and Mechanical Properties of EVA
    Liu, Yilin
    Li, Bin
    Xu, Miaojun
    Wang, Lili
    [J]. MATERIALS, 2020, 13 (05)