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Continuous hydrogenation of organic compounds in supercritical fluids

被引：130
|
作者：
Hitzler, MG [1 ]
Poliakoff, M [1 ]
机构：
[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND
来源：
CHEMICAL COMMUNICATIONS | 1997年 / 17期
关键词：
D O I：
10.1039/a704371f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A small flow reactor (5 ml volume) is used for continuous hydrogenation in supercritical CO2 or propane with polysiloxane-supported noble metal catalysts; a wide range of organic functionalities can be hydrogenated with good throughput (up to 1200 ml h(-1) in favourable cases) and the various parameters (temperature, pressure, concentration of H-2, etc.) can be controlled independently to optimise the selectivity for a particular product.
引用
收藏
页码：1667 / 1668
页数：2
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