Complexation between hydrogensulfated fullerenol and poly(4-vinylpyridine)

被引：0
|
作者：
Huang, XD
Goh, SH [1 ]
Lee, SY
Huan, CHA
机构：
[1] Natl Univ Singapore, Dept Chem, Singapore 119260, Singapore
[2] Natl Univ Singapore, Dept Phys, Singapore 119260, Singapore
来源：
MACROMOLECULAR CHEMISTRY AND PHYSICS | 2000年 / 201卷 / 02期
关键词：
D O I：
10.1002/(SICI)1521-3935(20000201)201:2<281::AID-MACP281>3.0.CO;2-I
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A fullerene (C60) derivative, hydrogensulfated fullerenol, has been complexed with poly(4-vinylpyridine) (P4VPy) through a supramolecular approach. The complexes are formed by mixing the N,N-dimethylformamide (DMF) solutions of P4VPy and hydrogensulfated fullerenol with multiple -OSO3H groups. Glass transition temperatures can not be detected in all complexes due to the strong interaction between the two components. Both Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy demonstrated the ionic nature of the interaction in the complexes.
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页码：281 / 287
页数：7
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