Biodiesel production from waste frying oil using waste animal bone and solar heat

被引:62
|
作者
Corro, Grisel [1 ]
Sanchez, Nallely [1 ]
Pal, Umapada [2 ]
Banuelos, Fortino [1 ]
机构
[1] Benemerita Univ Autonoma Puebla, Inst Ciencias, Puebla 72000, Mexico
[2] Benemerita Univ Autonoma Puebla, Inst Fis, Puebla 72570, Mexico
关键词
Low cost biodiesel; Waste frying oil; Waste animal bones; Hydroxyapatite; SOYBEAN OIL; CATALYSTS; TRANSESTERIFICATION; ESTERIFICATION; TECHNOLOGIES; METHANOL; BIOMASS; FTIR; ACID;
D O I
10.1016/j.wasman.2015.02.001
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A two-step catalytic process for the production of biodiesel from waste frying oil (WFO) at low cost, utilizing waste animal-bone as catalyst and solar radiation as heat source is reported in this work. In the first step, the free fatty acids (FFA) in WFO were esterified with methanol by a catalytic process using calcined waste animal-bone as catalyst, which remains active even after 10 esterification runs. The trans-esterification step was catalyzed by NaOH through thermal activation process. Produced biodiesel fulfills all the international requirements for its utilization as a fuel. A probable reaction mechanism for the esterification process is proposed considering the presence of hydroxyapatite at the surface of calcined animal bones.(c) 2015 Elsevier Ltd, All rights reserved.
引用
收藏
页码:105 / 113
页数:9
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