Construction of energy matrix for complex atoms in space of (nd+n's)(N+2)+Sigma(i,j)nd(N+2-wi-wj)n(i)l(i)(wi)n(j)l(j)(wj) (where w(i)+w(j)<=2) configurations

A method of parametrization of interactions in the fine-structure of 3d-atoms is extended to the model space of configurations (nd + n's)(N+2) + (i,j)Sigma nd(N+2-wi-wj)n(i)(wi)n(j)l(j)(w)j. It accounts for the first- as well as the second-order effects of the perturbation theory. The close analogy to the parametrization of the hyperfine structure interactions is shortly discussed, this can serve as a sensitive test for the quality of fine structure analysis.