Physico-chemical properties of binary mixtures of tert-butanol with (nitro-, chloro- and bromo-) benzene at 303.15 K and 308.15 K

被引：0
|
作者：
Saini, Balwinder [2 ]
Sharma, Renu [1 ]
Bamezai, Rajinder K. [1 ]
机构：
[1] Univ Jammu, Dept Chem, Jammu 180006, India
[2] Lovely Profess Univ, Dept Chem, Jalandhar 144411, India
来源：
INDIAN JOURNAL OF PURE & APPLIED PHYSICS | 2015年 / 53卷 / 12期
关键词：
Isentropic compressibility; Excess molar volume; Excess Gibbs free energy of activation; Speed of sound; LIQUID MIXTURES; ISENTROPIC COMPRESSIBILITIES; EXCESS VOLUMES; MOLECULAR INTERACTION; PLUS CYCLOHEXANONE; VISCOSITY; ALCOHOLS; ETHYL; NITROBENZENE; TEMPERATURES;
D O I：
暂无
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
The density (rho), viscosity (eta) and speed of sound (u) of three binary liquid mixtures of tert-butanol with (nitro-, chloro- and bromo-) benzene have been measured over the entire composition range at 303.15 K, 308.15 K and atmospheric pressure. From the experimental data, excess molar volume (V-E), isentropic compressibility (kappa(s)), excess Gibbs free energy of activation (Delta G*(E)), deviation parameters like viscosity (Delta eta), speed of sound (Delta u) and isentropic compressibilitY (Delta kappa(s)) are obtained. These functions have been fitted to Redlich-Kister polynomial equation to derive the coefficients and standard deviations.
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页码：790 / 795
页数：6
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